Research Progress of Micro-arc Oxidation Surface Treatment of Magnesium Alloy_Journal of Biomedical Engineering

Authors：

LUYutong ^1,2 , LITao ¹ , SHANGXiaopan ^1,2 , WANGYafeng ¹ ,  CAIXingwei ¹

1. PLA Rocket Force General Hospital, Beijing 100088, China;
2. Graduate School of Jinzhou Medical University, Jinzhou 121001, China;

Corresponding author：

CAIXingwei, Email: 82176566@qq.com

Keywords：

magnesium alloy; micro-arc oxidation; micro-arc oxidation coating

DOI：

10.7507/1001-5515.20160163

Video：

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An oxide ceramic coating can be formed on the surface of magnesium alloy by micro-arc oxidation so that the corrosion resistance of the magnesium alloy can be enhanced. In this paper, a general overview of the surface treatment of micro-arc oxidation on the surface of magnesium alloy is presented, the related research on the treatment of several kinds of magnesium alloys is introduced in detail, and a brief introduction of biological activity of magnesium alloy due to micro-arc oxidation is given. Finally, the technical advantages and existing problems are summarized.

Citation： LU Yutong, LI Tao, SHANG Xiaopan, WANG Yafeng, CAI Xingwei. Research Progress of Micro-arc Oxidation Surface Treatment of Magnesium Alloy. Journal of Biomedical Engineering, 2016, 33(5): 1016-1019. doi: 10.7507/1001-5515.20160163 Copy

1.	RAZAVI M, FATHI M, SAVABI O, et al. Nanostructured merwinite bioceramic coating on Mg alloy deposited by electrophoretic deposition[J]. Ceramics International, 2014, 40(7, A):9473-9484.
2.	张涛, 武肖娜, 尹庆水, 等.镁合金AZ31B材料表性与成骨细胞的粘附[J].中国组织工程研究, 2013, 17(12):2123-2130.
3.	LIN D J, HUNG F Y, LUI T S, et al. Heat treatment mechanism and biodegradable characteristics of ZAX1330 Mg alloy[J]. Mater Sci Eng C Mater Biol Appl, 2015, 51:300-308.
4.	刘睿, 姜科, 赵保东, 等.医用新型Mg-Li-Ca合金材料体外生物相容性及生物活性评价[J].中国组织工程研究, 2014, 18(52):8409-8413.
5.	LI Honglong, PAN Haobo, NING Chengyun, et al. Magnesium with micro-arc oxidation coating and polymeric membrane:an in vitro study on microenvironment[J]. J Mater Sci Mater Med, 2015, 26(3):147.
6.	章珏, 梁金, 刘红霞, 等.镁合金表面处理技术的进展[J].轻合金加工技术, 2014, 42(3):19-23.
7.	BAGHERI H R, ALIOFKHAZRAEI M, GHEYTANI M, et al. Growth and internal microstructure of micro-arc oxidized MgO-based nanocomposite coating[J]. Surf Coat Technol, 2015, 283:1-9.
8.	GAO Hai-tao, ZHANG Meng, YANG Xin, et al. Effect of Na₂SiO₃ solution concentration of micro-arc oxidation process on lap-shear strength of adhesive-bonded magnesium alloys[J]. Appl Surf Sci, 2014, 314:447-452.
9.	刘胤, 刘时美, 于鲁萍, 等.镁合金的腐蚀与微弧氧化膜层研究[J].中国腐蚀与防护学报, 2015, 35(2):99-105.
10.	VEYS-RENAUX D, BARCHICHE C E, ROCCA E. Corrosion behavior of AZ91 Mg alloy anodized by low-energy micro-arc oxidation:Effect of aluminates and silicates[J]. Surf Coat Technol, 2014, 251:232-238.
11.	张荣发, 单大勇, 陈荣石, 等.电参数对镁合金微弧氧化膜厚度的影响[J].中国有色金属学报, 2007, 17(10):1574-1579.
12.	董海荣, 马颖, 郭惠霞, 等.AZ91D镁合金微弧氧化膜的致密性及其对耐蚀性的影响[J].中国有色金属学报, 2015, 25(4):844-851.
13.	李雯霞.工艺因素对镁合金微弧氧化膜层性能的影响[J].中国铸造装备与技术, 2011(2):1-4.
14.	WANG Z X, LV W G, CHEN J. et al. Characterization of ceramic coating on ZK60 magnesium alloy prepared in a dual electrolyte system by micro-arc oxidation[J]. Rare Metals, 2013, 32(5):459-464.
15.	时惠英, 惠利芳, 蒋百灵, 等.AZ31B镁合金表面微弧电泳复合膜层微观结构及耐腐蚀性表征[J].稀有金属材料与工程, 2015, 44(7):1679-1684.
16.	VEYS-RENAUX D, ROCCA E, HENRION G. Micro-arc oxidation of AZ91 Mg alloy:An in-situ electrochemical study[J]. Electrochem Commun, 2013, 31:42-45.
17.	杜翠玲, 陈静, 汤莉, 等.正向电压对ZK60镁合金微弧氧化过程及膜层的影响[J].中国有色金属学报, 2014, 24(5):1118-1126.
18.	WILLBOLD E, GU X, ALBERT D, et al. Effect of the addition of low rare earth elements (lanthanum, neodymium, cerium) on the biodegradation and biocompatibility of magnesium[J]. Acta Biomater, 2015, 11:554-562.
19.	GRIFFITHS D. Explaining texture weakening and improved formability in magnesium rare earth alloys[J].材料科学与工艺, 2015, 31(1):10-24.
20.	贾方舟, 佟玮, 张联英, 等.AZ31和稀土镁合金微弧氧化膜的对比研究[J].材料导报B:研究篇, 2015, 29(4):46-49, 54.
21.	贾方舟, 孙国进, 张联英, 等.石蜡封孔的稀土镁合金微弧氧化膜的耐蚀性[J].材料保护, 2014, 47(10):9-11.
22.	任晓东, 赵亚亚, 李雪松.钇对Mg-2Zn-0.5Ca-Y合金表面微弧氧化膜性能的影响[J].电镀与环保, 2015, 35(2):34-36.
23.	宗阳.可降解骨内植入材料用镁合金JDBM表面改性的研究[D].上海:上海交通大学, 2011.
24.	JEONG Y S, KIM W J. Enhancement of mechanical properties and corrosionresistance of Mg-Ca alloys through microstructural refinement by indirectextrusion[J]. Corrosion Science, 2014, 82:392-403.
25.	贾昭君, 李明, 刘倩, 等.新型可降解Mg-1Ca合金微弧氧化工艺初探[J].稀有金属材料与工程, 2014, 43(S1):270-275.
26.	曲彪, 常乐, 张淑芳, 等.医用Mg-1.0Ca合金微弧氧化膜生物相容性研究[J].稀有金属材料与工程, 2014, 43(S1):357-360.
27.	JIA Z J, LI M, LIU Q, et al. Micro-arc oxidization of a novel Mg-1Ca alloy in three alkaline KF electrolytes:Corrosion resistance and cytotoxicity[J]. Appl Surf Sci, 2014, 292:1030-1039.
28.	ZENG Rongchang, SUN Lu, ZHENG Yufeng, et al. Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank's solution:The influence of microstructural features[J]. Corrosion science, 2014, 79:69-82.
29.	SHI L, XU Y, LI K, et al. Mg-Li alloy by micro-arc oxidation[J]. Current Applied Physics, 2010, 10:719-723.
30.	RAMA KRISHNA L, POSHAL G, JYOTHIRMAYI A, et al. Relative hardness and corrosion behavior of micro arc oxidation coatings deposited on binary and ternary magnesium alloys[J]. Mater Des, 2015, 77:6-14.
31.	于景媛, 王建中, 李强, 等.Mn含量对梯度多孔Mg-Mn合金微弧氧化膜组织与性能的影响[J].材料热处理学报, 2015, 36(4):179-184.
32.	黄震, 吴凤鸣, 柳麟翔, 等.微弧氧化AZ91D镁合金对成骨细胞早期粘附的影响[J].口腔医学, 2009, 29(4):180-182, 198.
33.	康帅, 臧圣奇, 万鹏, 等.镁基合金生物相容性的初步研究[J].牙体牙髓牙周病学杂志, 2015, 25(4):215-222, 205.
34.	PAN Y K, CHEN C Z, WANG D G, et al. Preparation and bioactivity of micro-arc oxidation calcium phosphate coatings[J]. Mater Chem Phys, 2013, 141:842-849.
35.	RAZAVI M, FATHI M, SAVABI O, et al. Surface microstructure and in vitro analysis of nanostructured akermanite (Ca₂MgSi₂O₇) coating on biodegradable magnesium alloy for biomedical applications[J]. Colloids Surf B Biointerfaces, 2014, 117:432-440.
36.	RAZAVI M, FATHI M, SAVABI O, et al. In vitro study of nanostructured diopside coating on Mg alloy orthopedic implants[J]. Mater Sci Eng C Mater Biol Appl, 2014, 41:168-177.
37.	MA Xun, ZHU Shijie, WANG Liguo, et al. Synthesis and properties of a bio-composite coating formed on magnesium alloy by one-step method of micro-arc oxidation[J]. J Alloys Compd, 2014, 590:247-253.

1. RAZAVI M, FATHI M, SAVABI O, et al. Nanostructured merwinite bioceramic coating on Mg alloy deposited by electrophoretic deposition[J]. Ceramics International, 2014, 40(7, A):9473-9484.
2. 张涛, 武肖娜, 尹庆水, 等.镁合金AZ31B材料表性与成骨细胞的粘附[J].中国组织工程研究, 2013, 17(12):2123-2130.
3. LIN D J, HUNG F Y, LUI T S, et al. Heat treatment mechanism and biodegradable characteristics of ZAX1330 Mg alloy[J]. Mater Sci Eng C Mater Biol Appl, 2015, 51:300-308.
4. 刘睿, 姜科, 赵保东, 等.医用新型Mg-Li-Ca合金材料体外生物相容性及生物活性评价[J].中国组织工程研究, 2014, 18(52):8409-8413.
5. LI Honglong, PAN Haobo, NING Chengyun, et al. Magnesium with micro-arc oxidation coating and polymeric membrane:an in vitro study on microenvironment[J]. J Mater Sci Mater Med, 2015, 26(3):147.
6. 章珏, 梁金, 刘红霞, 等.镁合金表面处理技术的进展[J].轻合金加工技术, 2014, 42(3):19-23.
7. BAGHERI H R, ALIOFKHAZRAEI M, GHEYTANI M, et al. Growth and internal microstructure of micro-arc oxidized MgO-based nanocomposite coating[J]. Surf Coat Technol, 2015, 283:1-9.
8. GAO Hai-tao, ZHANG Meng, YANG Xin, et al. Effect of Na₂SiO₃ solution concentration of micro-arc oxidation process on lap-shear strength of adhesive-bonded magnesium alloys[J]. Appl Surf Sci, 2014, 314:447-452.
9. 刘胤, 刘时美, 于鲁萍, 等.镁合金的腐蚀与微弧氧化膜层研究[J].中国腐蚀与防护学报, 2015, 35(2):99-105.
10. VEYS-RENAUX D, BARCHICHE C E, ROCCA E. Corrosion behavior of AZ91 Mg alloy anodized by low-energy micro-arc oxidation:Effect of aluminates and silicates[J]. Surf Coat Technol, 2014, 251:232-238.
11. 张荣发, 单大勇, 陈荣石, 等.电参数对镁合金微弧氧化膜厚度的影响[J].中国有色金属学报, 2007, 17(10):1574-1579.
12. 董海荣, 马颖, 郭惠霞, 等.AZ91D镁合金微弧氧化膜的致密性及其对耐蚀性的影响[J].中国有色金属学报, 2015, 25(4):844-851.
13. 李雯霞.工艺因素对镁合金微弧氧化膜层性能的影响[J].中国铸造装备与技术, 2011(2):1-4.
14. WANG Z X, LV W G, CHEN J. et al. Characterization of ceramic coating on ZK60 magnesium alloy prepared in a dual electrolyte system by micro-arc oxidation[J]. Rare Metals, 2013, 32(5):459-464.
15. 时惠英, 惠利芳, 蒋百灵, 等.AZ31B镁合金表面微弧电泳复合膜层微观结构及耐腐蚀性表征[J].稀有金属材料与工程, 2015, 44(7):1679-1684.
16. VEYS-RENAUX D, ROCCA E, HENRION G. Micro-arc oxidation of AZ91 Mg alloy:An in-situ electrochemical study[J]. Electrochem Commun, 2013, 31:42-45.
17. 杜翠玲, 陈静, 汤莉, 等.正向电压对ZK60镁合金微弧氧化过程及膜层的影响[J].中国有色金属学报, 2014, 24(5):1118-1126.
18. WILLBOLD E, GU X, ALBERT D, et al. Effect of the addition of low rare earth elements (lanthanum, neodymium, cerium) on the biodegradation and biocompatibility of magnesium[J]. Acta Biomater, 2015, 11:554-562.
19. GRIFFITHS D. Explaining texture weakening and improved formability in magnesium rare earth alloys[J].材料科学与工艺, 2015, 31(1):10-24.
20. 贾方舟, 佟玮, 张联英, 等.AZ31和稀土镁合金微弧氧化膜的对比研究[J].材料导报B:研究篇, 2015, 29(4):46-49, 54.
21. 贾方舟, 孙国进, 张联英, 等.石蜡封孔的稀土镁合金微弧氧化膜的耐蚀性[J].材料保护, 2014, 47(10):9-11.
22. 任晓东, 赵亚亚, 李雪松.钇对Mg-2Zn-0.5Ca-Y合金表面微弧氧化膜性能的影响[J].电镀与环保, 2015, 35(2):34-36.
23. 宗阳.可降解骨内植入材料用镁合金JDBM表面改性的研究[D].上海:上海交通大学, 2011.
24. JEONG Y S, KIM W J. Enhancement of mechanical properties and corrosionresistance of Mg-Ca alloys through microstructural refinement by indirectextrusion[J]. Corrosion Science, 2014, 82:392-403.
25. 贾昭君, 李明, 刘倩, 等.新型可降解Mg-1Ca合金微弧氧化工艺初探[J].稀有金属材料与工程, 2014, 43(S1):270-275.
26. 曲彪, 常乐, 张淑芳, 等.医用Mg-1.0Ca合金微弧氧化膜生物相容性研究[J].稀有金属材料与工程, 2014, 43(S1):357-360.
27. JIA Z J, LI M, LIU Q, et al. Micro-arc oxidization of a novel Mg-1Ca alloy in three alkaline KF electrolytes:Corrosion resistance and cytotoxicity[J]. Appl Surf Sci, 2014, 292:1030-1039.
28. ZENG Rongchang, SUN Lu, ZHENG Yufeng, et al. Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank's solution:The influence of microstructural features[J]. Corrosion science, 2014, 79:69-82.
29. SHI L, XU Y, LI K, et al. Mg-Li alloy by micro-arc oxidation[J]. Current Applied Physics, 2010, 10:719-723.
30. RAMA KRISHNA L, POSHAL G, JYOTHIRMAYI A, et al. Relative hardness and corrosion behavior of micro arc oxidation coatings deposited on binary and ternary magnesium alloys[J]. Mater Des, 2015, 77:6-14.
31. 于景媛, 王建中, 李强, 等.Mn含量对梯度多孔Mg-Mn合金微弧氧化膜组织与性能的影响[J].材料热处理学报, 2015, 36(4):179-184.
32. 黄震, 吴凤鸣, 柳麟翔, 等.微弧氧化AZ91D镁合金对成骨细胞早期粘附的影响[J].口腔医学, 2009, 29(4):180-182, 198.
33. 康帅, 臧圣奇, 万鹏, 等.镁基合金生物相容性的初步研究[J].牙体牙髓牙周病学杂志, 2015, 25(4):215-222, 205.
34. PAN Y K, CHEN C Z, WANG D G, et al. Preparation and bioactivity of micro-arc oxidation calcium phosphate coatings[J]. Mater Chem Phys, 2013, 141:842-849.
35. RAZAVI M, FATHI M, SAVABI O, et al. Surface microstructure and in vitro analysis of nanostructured akermanite (Ca₂MgSi₂O₇) coating on biodegradable magnesium alloy for biomedical applications[J]. Colloids Surf B Biointerfaces, 2014, 117:432-440.
36. RAZAVI M, FATHI M, SAVABI O, et al. In vitro study of nanostructured diopside coating on Mg alloy orthopedic implants[J]. Mater Sci Eng C Mater Biol Appl, 2014, 41:168-177.
37. MA Xun, ZHU Shijie, WANG Liguo, et al. Synthesis and properties of a bio-composite coating formed on magnesium alloy by one-step method of micro-arc oxidation[J]. J Alloys Compd, 2014, 590:247-253.

Journal of Biomedical Engineering

Research Progress of Micro-arc Oxidation Surface Treatment of Magnesium Alloy

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